Chapter 1 of Warriors Orochi 3 Ultimate
Ma Chao – Start story mode.
Hanbei Takenaka – Start story mode.
Sima Zhao – Start Story mode.
Pang De – Battle of Yiling
Ma Dai – Battle of Yiling
Kunoichi – Battle of Yiling
Zhang Liao – Battle of Ueda Castle
Taishi Ci – Battle of Ueda Castle
Wang Yuanji – Battle of Ueda Castle
Zhuge Dan – Battle of Ueda Castle
Sakon Shima – Battle of Ueda Castle
Kanbei Kuroda – Battle of Dongkou
Xu Huang – Battle of Dongkou
Deng Ai – Battle of Dongkou
Jia Xu – Battle of Dongkou
Ginchiyo Tachibana – Battle of Dongkou
Huang Gai – Battle of Dongkou
Huang Zhong – Complete the Battle of Tetorigawa to unlock Battle of Yiling Redux. Complete that to unlock.
Xu Shu – Complete the Battle of Tetorigawa to unlock Battle of Yiling Redux. Complete that to unlock.
Masanori Fukushima – Battle of Shouchun
Taigong Wang – Battle of Shouchun
Yoshitsune Minamoto – Battle of Shouchun
Ranmaru Mori – Battle of Nagashino
Guo Huai – Battle of Nagashino
Yukimura Sanada – Battle of Nagashino
Zhou Tai – Battle of Nagashino
Hideyoshi Toyotomi – Battle of Nagashino
Yoshihiro Shimazu – Battle of Odawara Castle
Sun Shangxiang – Battle of Odawara Castle
Xiaoquiao – Battle of Odawara Castle
Ding Fen – Battle of Odawara Castle
Kai – Battle of Odawara Castle
Chapter 2 of Warriors Orochi 3 Ultimate
Nemea – Battle of Kyushu
Goemon Ishikawa – Battle of Kyushu
Bao Sanniang – Battle of Kyushu
Wei Yan – Battle of Nanzhong
Meng Huo – Battle of Nanzhong
Zhurong – Battle of Nanzhong
Benkei – Battle of Anegawa
Zuo Ci – Battle of Anegawa
Ryu Hayabusa – Battle of Anegawa
Toshiie Maeda – Battle of Anegawa
Cai Wenji – Battle of Anegawa
Kanatsugu Naoe – Battle of Anegawa
Joan of Arc – Battle of Mt. Dingjun
Guan Yu – Battle of Mt. Dingjun
Cao Ren – Battle of Mt. Dingjun
Sun Quan – Battle of Mt. Dingjun
Xiahou Ba – Battle of Mt. Dingjun
Ayane – Battle of Hasedo
Liu Shan – Battle of Hasedo
Nagamasa Azai – Battle of Hasedo
Kiyomasa Kato – Battle of Hasedo
Muneshige Tachibana – After the Battle of Kyushu, improve relationships between Xiaoqiao, Sun Shangxiang, and Ginchiyo Tachibana to level two. Then, complete Battle of Mt. Xingshi.
Musashi Miyamoto – Complete the Rescue at Dongkou and then complete Battle of Odawara Castle Redux.
Lianshi – Complete the Rescue at Taoshui and then Battle of Nagashino Redux. You need to rendezvous with Lianshi when she reappears at the end of the battle.
Seimei Abe – Struggle for Ueda Castle
Sanzang – Level the relationship between Goemon Ishikawa and Hideyoshi Toyotomi to level 2. Then, complete the Battle of Taoshui.
Ling Tong – Level the relationship between Goemon Ishikawa and Hideyoshi Toyotomi to level 2. Then, complete the Battle of Taoshui.
Yueying – Level relationship between Zuo Ci, Benkei, and Xu Huang to level 2. Then, complete the Chaos at Tetorigawa.
Lu Meng – Complete the Retreat from Mt. Niutou. Then, the Battle of Hasedo Redux.
Magoichi Saika – Complete the Heroes of Komaki-Nagukute. Then, the Battle of Dingjun Redux.
Gan Ning – Level relationship between Lu Meng, Lianshi, and Masanori Fukushima to level 2. Then, complete the Battle of Mikatagahara.
Rachel – Level relationship between Ding Feng and Lianshi to level 2. Then, complete the battle of Jiangdong.
Xiahou Yuan – Level relationship between Xiahou Ba and Magoichi Saika to level 2. Then, complete the Battle of Nanjun.
Zhang He – Battle of Xuchang
Xingcai – Battle of Xuchang
Shuten Doji – Battle of Xuchang
Oichi – Battle of Xuchang
Nene – Battle of Xuchang
Katsuie Shibata – Battle of Xuchang
Da Ji – Battle of Sekigahara
Himiko – Battle of Sekigahara
Achilles – Battle of Sekigahara
Motonari Mori – Battle of Sekigahara
Masamune Date – Battle of Luoyang
Keiji Maeda – Battle of Luoyang
Kojiro Sasaki – Level relationship between Zhang He, Meng Huo, and Zhurong to level 2. Then, complete the Purge at Nanzhong.
Jian Wei – Battle of Xuchang Redux
Guan Ping – Level relationship between Xingcai and Keiji Maeda to level 2. Then, complete Battle of Jietjing.
Yuan Shao – Level relationship between Motonari Mori and Jia Xu to level 2. Then, complete Battle of Jiange.
Chapter 3 of Warriors Orochi 3 Ultimate
Xu Zhu – Battle of Tong Gate
Sima Shi – Battle of Tong Gate
Mitsunari Ishida – Battle of Tong Gate
Zhao Yun – Battle of Yangping Gate
Zhang Fei – Battle of Yangping Gate
Tadakatsu Honda – Battle of Yangping Gate
Hanzo Hattori – Battle of Yangping Gate
Aya – Battle of Shizugatake
Sun Ce – Battle of Changban
Daqiao – Battle of Changban
Ujiyasu Hojo – Battle of Changban
Sun Jian – Battle of Honnoji
Nobunaga Oda – Battle of Honnoji
No – Battle of Honnoji
Fu Xi – Battle of Honnoji
Diaochan – Battle of Tong Gate Redux
Mitsuhide Akechi – Battle of Honnoji Redux
Sophitia Alexandra – Battle of Liaodong
Shennong – Level relationship between Fu Xi and Himiko to level 2. Then, complete Defense of Yanping Gate.
Okuni – Level relationship between Aya and Lianshi to level 2. Then, complete Battle of Luo Castle.
Kotaru Fuma – Level relationship between Ujiyasu Hojo and Ding Fend to level 2. Then, complete Siege of Shouchun.
Momiji – Battle of Wan Castle
Guan Suo – Complete the battle of Changban for Diaochan, then the Battle of Mt. Niutou.
Yoshimoto Imagawa – Level relationship between Liu Shan and Guan Suo to level 2. Then, complete the battle of Liang Province.
Motochika Chosokabe – Level relationship between Liu Shan and Guan Suo to level 2. Then, complete the battle of Liang Province.
Sterkenberg Cranach – Battle of Xu Province
Xiahou Dun – Battle of Fan Castle
Cao Cao – Battle of Fan Castle
Nuwa – Battle of Fan Castle
Kasumi – Battle of Yan Province
Zhuge Liang – Battle of Chengdu
Liu Bei – Battle of Chengdu
Dong Zhuo – Battle of Chengdu
Ieyasu Tokugawa – Battle of Chengdu
Cao Pi – Battle of Hulao Gate
Zhenji – Battle of Hulao Gate
Sima Yi – Battle of Hulao Gate
Kenshin Uesugi – Battle of Osaka Castle
Shingen Takeda – Battle of Osaka Castle
Lu Bu – Battle of Osaka Castle
Guo Jia – Battle of Fan Castle Redux
Ina – Rescue at Yiling
Zhang Jiao – Level relationship between Sima Yi and Masamune Date to level 2. Then, complete Battle of Guangzong.
Gracia – Level relationship between Sima Yi and Masamune Date to level 2. Then, complete Battle of Guangzong.
Dian Wei – Battle of Changban Redux
Chapter 4 of Warriors Orochi 3 Ultimate
Lu Xun – Level relationship between Mitsunari Ishida and Cao Pi to level 2. Then, complete the Battle of Hefei.
Pang Ton – Level relationship between Zhuge Liang, Hanzo Hattori, and Huang Zhong to level 2. Then, complete the Battle of Komaki-Nagakute.
Zhong Hui – Level relationship between Deng Ai, Mitsuhide Akechi, and Nagamasa Azai to level 2. Then, complete the Siege of Luoyang.
Wang Yi – Level relationship between No and Oichi to level 2. Then, complete Salvation at Nagashino.
Dodomeki – Complete the Slaying of the Hydra Alternate after finishing Chapter 3.
Gyuki – Complete the Slaying of the Hydra Alternate after finishing Chapter 3.
Orochi – Complete the World’s End having unlocked all other characters.
Orochi X – Complete the World’s End having unlocked all other characters.
Sun Wukong – Complete the World’s End having unlocked all other characters.
Kiyomori Taira – Complete the World’s End having unlocked all other characters.
Susano’o – Complete the World’s End having unlocked all other characters.
Nezha – Complete the World’s End having unlocked all other characters.
Chapter 7 of Warriors Orochi 3 Ultimate
Yinlong – Defense of the Mystic Realm
Human Nezha – War in the Mystic Realm
Chapter 8 of Warriors Orochi 3 Ultimate
Tamomo – Showdown at Odawara Castle
Kyubi – Escape from the Mystic Realm
Hundun – Get to level 4 of gauntlet mode.
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